MDCAT/ECAT/FSC Chapter-wise High-Yield Chemistry MCQs Quiz on Gaseous State

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💥MDCAT/ECAT Chemistry Chapter-wise High-Yield Chemistry MCQs on Gaseous State 🧬| Exam-Focused, 🎯 💯 Exam Booster🚀 Practice & Win 190+! 📚 Topper’s Choice

1️⃣ According to Graham’s Law of diffusion, the ratio of diffusion of H₂ and O₂ are respectively:
🟥 a) 1:2 
🟦 b) 2:1 
🟩 c) 1:4 
🟨 d) 4:1 

2️⃣ Collection of gas over water is an example of:
🟥 a) Graham’s law 
🟦 b) Dalton’s law 
🟩 c) Avogadro’s law 
🟨 d) Gay-Lussac law

3️⃣ The molar volume of oxygen gas is maximum at:
🟥 a) 0°C and 1 atm 
🟦 b) 0°C and 2 atm 
🟩 c) 25°C and 1 atm 
🟨 d) 25°C and 2 atm

4️⃣ The volume of gas would be theoretically zero at:
🟥 a) 0°C 
🟦 b) 0 K 
 🟩 c) 273 K 
🟨 d) 273°C

5️⃣If Kelvin temperature of ideal gas is doubled and pressure reduced to half, the volume will:
🟥 a) Remains same 
🟦 b) Double 
🟩 c) Reduced to half 
🟨 d) Four times ✅

6️⃣ The molar volume of oxygen gas is 22.4 dm³ at:
🟥 a) 0°C and 1 atm 
🟦 b) 25°C and 0.5 atm 
🟩 c) 0 K and 1 atm 
🟨 d) 25 K and 0.5 atm

7️⃣ Under similar conditions CH₄ gas diffuses … faster than SO₂ gas:
🟥 a) 1.5 times 
🟦 b) 2 times 
 🟩 c) 4 times 
🟨 d) 16 times

8️⃣ Which statement is INCORRECT about gas molecules?
🟥 a) They have large spaces 
🟦 b) They possess kinetic energy 
🟩 c) Their collision is elastic 
🟨 d) Their molar mass depends upon temperature 

9️⃣ The diffusion rate of C₃H₈ and CO₂ are same because:
🟥 a) Both are polyatomic gases 
🟦 b) Both are denser than air 
🟩 c) Both have same molar mass 
🟨 d) Both contain carbon atoms

1️⃣ 0️⃣ Real gas reaches ideal behavior at:
🟥 a) Low temperature and low pressure 
🟦 b) High temperature and high pressure 
🟩 c) Low temperature and high pressure 
🟨 d) High temperature and low pressure 

1️⃣ 1️⃣ If the ratio of the rates of diffusion of the two gases A and B is 4:1, the ratio of their densities is:
🟥 a) 1:16 
🟦 b) 1:4 
🟩 c) 1:8 
🟨 d) 1:2

12. Relative rates of diffusion of two gases X and Y are 3:2. If the density of Y is 27, the density of X is:
🟥 a) 27 
🟦 b) 54 
🟩 c) 4 
🟨 d) 12 

13. 1 liter of a gas weighs 2 g at 300 K and 1 atm. If pressure is made 75 atm, at which temperature will 1 L weigh 1 g?
🟥 a) 450 K 
 🟦 b) 800 K 
🟩 c) 600 K 
🟨 d) 900 K

14. Above Boyle temperature real gases show __________ deviation from ideal gases:
🟥 a) Positive 
🟦 b) Negative 
🟩 c) No 
🟨 d) Both positive and negative

15. What are the units of “b” in van der Waals equation?
🟥 a) L/mol 
 🟦 b) L mol 
🟩 c) 1/L mol 
🟨 d) L

16. The temperature at which a real gas obeys Boyle’s law or behaves ideally is called:
🟥 a) Boyle temperature 
 🟦 b) Charge temperature 
🟩 c) Critical temperature 
🟨 d) Absolute temperature

17. A gas of 2 moles occupies 500 ml at 300 K and 50 atm. Compressibility factor is:
🟥 a) 1.863 
🟦 b) 0.7357 
🟩 c) 0.5081 
🟨 d) 1.8754

18. The term that corrects for attractive forces in van der Waals equation is:
🟥 a) nb 
🟦 b) an²/V² 
🟩 c) –an²/V² 
🟨 d) –nb

19. The term “a/V²” in van der Waals equation is for:
🟥 a) Internal pressure 
🟦 b) Intermolecular attraction 
🟩 c) Temperature correction 
🟨 d) Both a and b

20. In van der Waals equation of state, the term that accounts for intermolecular force is:
🟥 a) (V – b) 
🟦 b) RT 
🟩 c) (P + a/V²)  
🟨 d) (RT)⁻¹

21. An ideal gas expands according to PV = constant. On expansion the temperature of gas:
🟥 a) Will rise 
🟦 b) Will remain constant  
🟩 c) Cannot be determined 
🟨 d) Will drop

22. A gas at 100 K is heated until 200 K. What happens to kinetic energy?
🟥 a) Halved 
🟦 b) Tripled 
🟩 c) Quadrupled 
🟨 d) Doubled 

23. PV/nRT is known as:
🟥 a) Temperature factor 
🟦 b) Compressibility factor  
🟩 c) Pressure factor 
🟨 d) Volume factor

24. The value of ‘b’ for CO₂ is 42.69 × 10⁻⁶ m³/mol. Volume of a molecule is:
🟥 a) 7.59 m³ 
🟦 b) 7.03 m³ 
🟩 c) 76.09 m³ 
🟨 d) 7.09 m³ 

25. Corresponding pressure of 32.8 psi in kPa is:
🟥 a) 226.085 kPa 
🟦 b) 2.23 kPa 
🟩 c) 1695.8 kPa 
🟨 d) None of these

26. Low atmospheric system is called:
🟥 a) Depression  
🟦 b) Atmosphere 
🟩 c) Both of them 
🟨 d) None of them

27. Which reduces force of attraction between gas molecules?
🟥 a) High pressure 
🟦 b) High temperature 
🟩 c) Low temperature 
🟨 d) All of them

28. At STP, 44.8 L of any gas weighs equal to:
🟥 a) 1 mole 
🟦 b) 1.5 mole 
🟩 c) 2 mole 
🟨 d) 3 mole

29. The random motion of gas molecules from one place to another is called:
🟥 a) Effusion 
🟦 b) Osmosis 
🟩 c) Diffusion 
🟨 d) All of them

30. The escape of gas molecules through a tiny hole into an evacuated chamber is called:
🟥 a) Effusion 
 🟦 b) Osmosis 
🟩 c) Diffusion 
🟨 d) All of them

31. The collision of ideal gas molecules are:
🟥 a) Elastic 
 🟦 b) Inelastic 
🟩 c) Both a and b 
🟨 d) None of them

32. When the pressure approaches zero, all gases reach a value of Z ………..
🟥 a) Less than 1 
🟦 b) Greater than 1 
🟩 c) Equal to 1 
🟨 d) None of them

33. Which increases force of attraction between gas molecules?
🟥 a) Low pressure 
🟦 b) High temperature 
🟩 c) Low temperature 
🟨 d) All of them

34. Out of the following, which molecule does NOT possess London forces?
🟥 a) He 
🟦 b) Ne 
 c) H₂ 
🟨 d) NH₃ 

35. The three variables of volume, pressure & temperature can be inter-related in one expression called:
🟥 a) Boyle’s law 
🟦 b) Charles’s law 
🟩 c) General gas law 
 🟨 d) Dalton’s law

36. The total pressure exerted by a mixture of gases is the sum of partial pressures of all gases. This is the statement of:
🟥 a) Dalton’s law  
🟦 b) Gay-Lussac’s law 
🟩 c) Avogadro’s law 
🟨 d) Graham’s law

37. The respiration process in living things is an application of:
🟥 a) Gay-Lussac’s law 
🟦 b) Graham’s law 
🟩 c) Avogadro’s law 
🟨 d) Dalton’s law 

38. The partial pressure of oxygen in air is:
🟥 a) 159.6 mm Hg 
 🟦 b) 259.6 mm Hg 
🟩 c) 359.6 mm Hg 
🟨 d) None of them

39. The partial pressure of water vapours in gases is called:
🟥 a) Surface tension 
🟦 b) Aqueous tension  
🟩 c) Atmospheric pressure 
🟨 d) None of them

40. The volume of reactant and product gases in a chemical reaction at given T and P are in small whole numbers. This is the statement of:
🟥 a) Gay-Lussac’s law 
 🟦 b) Graham’s law 
🟩 c) Avogadro’s law 
🟨 d) Ideal gas law

41. The density of a gas varies directly with:
🟥 a) Temperature 
🟦 b) Volume 
🟩 c) Pressure 
 🟨 d) All of them

42. The density of a gas varies inversely with:
🟥 a) Temperature  
🟦 b) Molecular weight 
🟩 c) Pressure 
🟨 d) All of them

43. At same T and P, two balloons filled with CH₄ and SO₂. If SO₂ escapes at 100 ml/s, CH₄ escapes at:
🟥 a) 50 ml/s 
🟦 b) 100 ml/s 
🟩 c) 200 ml/s 
 🟨 d) 400 ml/s

44. At high altitude, pilots may have uncomfortable breathing in non-pressurized cabin where O₂ partial pressure is around:
🟥 a) 159.6 mm Hg 
🟦 b) 150 mm Hg 
🟩 c) 250 mm Hg 
🟨 d) 100 mm Hg

45. Which property is same for both normal hydrogen and deuterium?
🟥 a) Boiling point 
🟦 b) Freezing point 
🟩 c) Bond energy 
🟨 d) Bond length 

46. For which type of gases the graph between P (x-axis) and PV/nRT (y-axis) is a horizontal line?
🟥 a) Ideal gases 
 🟦 b) Real gases 
🟩 c) Noble gases 
🟨 d) None of them

47. The molecular weight of a gas varies directly with:
🟥 a) Temperature 
🟦 b) Volume 
🟩 c) Pressure 
🟨 d) None of them

48. Equation used to determine molecular weight of a gas if density is given:
🟥 a) M.W = RTd/P 
 🟦 b) M.W = P/RTd 
🟩 c) M.W = RPd/T 
🟨 d) None of them

49. The molecular weight of a gas varies inversely with:
🟥 a) Temperature 
🟦 b) Molecular weight 
🟩 c) Pressure 
🟨 d) None of them

50. Which one of the following is a monoatomic gas?
🟥 a) Krypton 
 🟦 b) Hydrogen 
🟩 c) Nitrogen 
🟨 d) Fluorine

51. Which is an ideal gas?
🟥 a) CH₄ 
🟦 b) CO 
🟩 c) CO₂ 
🟨 d) None of them 

52. Which is a real gas?
🟥 a) H₂ 
🟦 b) O₂ 
🟩 c) He 
🟨 d) All of them 

53. A gas which does not obey gas laws at all T and P is called:
🟥 a) Perfect gas
 🟦 b) Real gas 
 🟩 c) Noble gas 
🟨 d) None of them

54. … temperature and … pressure make gases non-ideal:
🟥 a) Low, high 
 🟦 b) High, low 
🟩 c) Low, low 
🟨 d) High, high

55. Which one of the following is more ideal?
🟥 a) Polar gases 
🟦 b) Non-polar gases 
 🟩 c) Real gases 
🟨 d) None of them

56. Which one of the following is more non-ideal?
🟥 a) Polar gases 
🟦 b) Non-polar gases 
🟩 c) Inert gases 
🟨 d) None of them

57. Attractive forces between gas molecules over short distances are called:
🟥 a) Induced dipole 
🟦 b) van der Waals forces 
 🟩 c) Dipole-dipole force 
🟨 d) All of them

58. van der Waals forces are:
🟥 a) Permanent forces 
🟦 b) Temporary forces 
 🟩 c) Variable forces 
🟨 d) None of them

59. Weak short-range attractive forces in non-polar molecules/inert gases due to temporary dipoles are:
🟥 a) London forces 
🟦 b) Hydrogen bonding 
🟩 c) Induced forces 
🟨 d) None of them

60. London forces are also called:
🟥 a) Dipole-dipole force 
🟦 b) van der Waals forces 
 🟩 c) Hydrogen bonding 
🟨 d) All of them

61. The molar volume of CO₂ is maximum at:
🟥 a) STP 
🟦 b) 127ºC and 1 atm 
🟩 c) 0ºC and 2 atm 
🟨 d) 273ºC and 2 atm

62. Equation used to determine density of a gas:
🟥 a) d = MP/RT 
🟦 b) d = RT/MP 
🟩 c) d = MRT 
🟨 d) d = RP/MT

63. At constant pressure, at which temperature will volume of gas be twice of what it is at 0ºC?
🟥 a) 546ºC 
🟦 b) 200ºC 
🟩 c) 546 K  
🟨 d) 273 K

64. If absolute temperature of a gas is doubled and pressure reduced to half, volume will:
🟥 a) Be doubled 
🟦 b) Reduce to ¼ 
🟩 c) Remain unchanged 
🟨 d) Quadruple 

65. The temperature 273 K corresponds to:
🟥 a) 0ºC 
🟦 b) 273ºC 
🟩 c) 100ºC 
🟨 d) –273ºC

66. Order of diffusion rate of NH₃, SO₂, Cl₂, CO₂:
🟥 a) NH₃ > SO₂ > Cl₂ > CO₂ 
🟦 b) NH₃ > CO₂ > SO₂ > Cl₂ 
🟩 c) NH₃ > CO₂ > Cl₂ > SO₂ 
🟨 d) Cl₂ > SO₂ > CO₂ > NH₃

67. Which pair of gases has same rate of diffusion?
🟥 a) Cl₂ and CO₂ 
🟦 b) C₃H₈ and CO₂ 
 🟩 c) NH₃ and SO₂ 
🟨 d) Cl₂ and NH₃

68. Which gas has the slowest diffusion rate?
🟥 a) O₃ 
🟦 b) C₂H₂ 
🟩 c) C₂H₆ 
🟨 d) C₄H₁₀ 

69. Value of universal gas constant R is/are:
🟥 a) 8.3143 J·mol⁻¹·K⁻¹ 
🟦 b) 0.0821 atm·dm³·mol⁻¹·K⁻¹ 
🟩 c) 1.987 cal·mol⁻¹·K⁻¹ 
🟨 d) All of them 

70. Which gas has the fastest diffusion rate?
🟥 a) O₂ 
🟦 b) C₂H₄  
🟩 c) C₃H₆ 
🟨 d) C₄H₈

71. The compressibility factor for an ideal gas is:
🟥 a) 1.5 
🟦 b) 1 
 🟩 c) 1 
🟨 d) ∞

72. Pressure exerted by gas collected over water = 735 torr, dry gas = 705 torr. Aqueous tension is:
🟥 a) 1440 torr 
🟦 b) 35 torr 
🟩 c) 735 torr 
🟨 d) 30 torr 

73. Molecules of gas A travel 4× faster than gas B at same T. Ratio of molecular weights (MA/MB):
🟥 a) 4 
🟦 b) ¼ 
🟩 c) 16 
🟨 d) 1/16 

74. Mixture of H₂ and O₂ in 2:1 volume diffuses through porous partition. Composition of gas coming out initially:
🟥 a) 1:2 
🟦 b) 4:1 
🟩 c) 1:4 
🟨 d) 8:1 

75. Which property has same value for H₂ and D₂ at same P and T?
🟥 a) Molecular mass 
🟦 b) Average molecular speed 
🟩 c) Average molecular K.E  
🟨 d) Density

76. Pressure doubled, temperature halved simultaneously. Volume will be:
🟥 a) Same as before  
🟦 b) ¼th as before 
🟩 c) Twice as before 
🟨 d) None

77. A pressure of 0.101325 bar in atmospheres is:
🟥 a) 0.01 atm 
🟦 b) 1 atm 
🟩 c) 0.1 atm  
🟨 d) 10 atm

78. Under which conditions do real gases approach ideal behaviour?
🟥 a) 15 atm, 200 K 
🟦 b) 15 atm, 500 K 
🟩 c) 1 atm, 273 K 
🟨 d) 0.5 atm, 500 K 

79. According to kinetic theory at absolute zero temperature:
🟥 a) Molecular motion stops  
🟦 b) Liquid helium freezes 
🟩 c) Liquid hydrogen freezes 
🟨 d) Water freezes

80. Boyle’s law is applicable in:
🟥 a) Isochoric process 
🟦 b) Isobaric process 
🟩 c) Isomeric process 
🟨 d) Isothermal process 

81. Densities of two gases are in ratio 1:16. Ratio of their diffusion rates is:
🟥 a) 1:16 
🟦 b) 1:4 
🟩 c) 16:1 
🟨 d) 4:1 

82. Dimensions of pressure are same as:
🟥 a) Energy 
🟦 b) Force per unit volume 
🟩 c) Mass per unit volume 
🟨 d) Force per unit area 

83. Atmospheric pressure experienced by human body is:
🟥 a) 14.7 psi  
🟦 b) 14.7 torr 
🟩 c) 0.95 atm 
🟨 d) 2 Pa

84. Volume of gas at 30°C is X L. Volume becomes half at:
🟥 a) –121.5°C  
🟦 b) 60°C 
🟩 c) 15°C 
🟨 d) None

85. Value of standard pressure in kilopascal is:
🟥 a) 1.01325 × 10²  
🟦 b) 1.01325 × 10⁵ 
🟩 c) 1.01325 × 10⁶ 
🟨 d) 14.7

86. Molecules of gas A travel 8× faster than gas B at same T. Ratio of molecular weights (MA/MB):
🟥 a) 1/64  
🟦 b) 1/32 
🟩 c) 32 
🟨 d) 64

87. Two spacecrafts: 10 m³ at 50 kPa, 30 m³ at 100 kPa. After connection, pressure is:
🟥 a) 150 kPa 
🟦 b) 75 kPa 
🟩 c) 87.5 kPa  
🟨 d) 100 kPa

88. Coldest temperature at which all molecular motion ceases is:
🟥 a) –273.15°C 
🟦 b) –459.7°C 
🟩 c) 0 K 
🟨 d) All of them 

89. 100 ml H₂ effuses 4× faster than 100 ml unknown gas. Molecular weight of unknown gas:

🟥 a) 28 g 
🟦 b) 64 g 
🟩 c) 32 g  
🟨 d) 80 g

90. Absolute temperature doubled, pressure increased 4×. Volume is:
🟥 a) Remains unchanged 
🟦 b) Four times 
🟩 c) Double 
🟨 d) Half 

91. The two gases which have the same molecular mass will have same:
🟥 a) Boiling point 
🟦 b) Diffusion rate 
🟩 c) Effusion rate 
🟨 d) Both b and c 

92. A gas is heated so that its volume halves and absolute temperature doubles. The pressure of the gas is:
🟥 a) Becomes half 
🟦 b) Becomes 2 times 
🟩 c) Becomes 4 times 
🟨 d) Remains same

93. The value of universal gas constant depends upon:
🟥 a) Temperature of the gas 
🟦 b) Volume of the gas 
🟩 c) Number of moles of gas 
🟨 d) None of these 

94. Which process weakens the force of attraction between particles?
🟥 a) Evaporation 
🟦 b) Freezing 
🟩 c) Condensation 
🟨 d) Crystallization

95. The relative rate of diffusion of H₂ and O₂ is:
🟥 a) 4:1 
🟦 b) 1:4 
🟩 c) 1:2 
🟨 d) 1:8

96. Hydrogen gas diffuses 6 times faster than gas X. The molecular mass of X is:
🟥 a) 10 
🟦 b) 72  
🟩 c) 32 
🟨 d) None of them

97. Heavy hydrogen (D₂) diffuses … times slower than H₂:
🟥 a) 1.41  
🟦 b) 2 
🟩 c) 4 
🟨 d) 2.5

98. … law is helpful in separating different isotopes of a gas:
🟥 a) Graham’s law  
🟦 b) Avogadro’s law 
🟩 c) Dalton’s law 
🟨 d) None

99. … is the weakest intermolecular force:
🟥 a) DDI 
🟦 b) LDF  
🟩 c) HBI 
🟨 d) IDI

100. The molar volume of CO₂ is maximum at:
🟥 a) 227ºC and 1 atm  
🟦 b) 0ºC and 2 atm 
🟩 c) –273ºC and 2 atm 
🟨 d) STP

✅ Answer Key with Short Reasons

1️⃣(Answer, d) 4:1 → Diffusion rate ∝ 1/√M; H₂ lighter than O₂.
r/r= √M/√M ⇒ r/r= √32/√2 ⇒ r/r= √16 ⇒ r/r= 4:1
2️⃣(Answer, b) Dalton’s law → Dry gas pressure = moist gas – water vapour pressure.
Collection of gas over water is an example of Dalton’s law. The pressure of dry gas is calculated by using Dalton’s law.
Pdry gas = Pmoist gas – Pwater vapours

3️⃣(Answer, c) 25°C & 1 atm → Higher T, lower P → maximum molar volume.
The molar volume of a gas varies directly with temperature and varies inversely with pressure. The molar volume of a gas is maximum at highest temperature and least pressure. In option c and d, temperature is highest hence deciding factor will be pressure which is least in option c.
4️⃣(Answer, b) 0 K → Absolute zero → theoretical zero volume.
The volume of gas would be theoretically zero at 0 K (-273°C).
5️⃣(Answer, d) Four times → V ∝ T/P; doubling T and halving P quadruples V.
PV=nRT ⇒ PV = T (R and n = constant) ⇒ V = T/P ⇒ V = 2/ ½ = 2 x 2 = 4
Thus, doubling the Kelvin temperature and halving the pressure quadruples the volume.
6️⃣(Answer, a) 0°C & 1 atm → STP conditions → 22.4 dm³ molar volume.
The molar volume of a gas is 22.4 dm3 at STP i.e. at 0°C and 1 atm.
7️⃣(Answer, b) 2 times → √(64/16) = 2; CH₄ diffuses twice as fast as SO₂.
r/r= √M/√M ⇒ r/r= √64/√16 ⇒ r/r= √4 ⇒ r/r2= 2
8️⃣(Answer, d) Molar mass independent of T → Mass is constant, not affected by temperature.
9️⃣(Answer, c) Same molar mass (44 g/mol) → Equal diffusion rates.
The rate of diffusion depends upon molar masses of gases. The gases with same molar masses would have same rate of diffusion. The given gases ethane (C₃H) and CO have same molar mass of 44 gmol¹.
1️⃣0️⃣(Answer, d) High T & low P → Conditions where real gases behave ideally.
1️⃣1️⃣1:16 → Graham’s law: diffusion rate ∝ √(1/density). Ratio 4:1 → density ratio 1:16.
1️⃣2️⃣ → From r/r = √(d/d), solving gives d = 12.
1️⃣3️⃣ 450 K → Using PV = nRT relation, calculation gives T₂ = 450 K.
1️⃣4️⃣ Positive deviation → Above Boyle temperature, compressibility factor Z > 1.
1️⃣5️⃣L/mol → b represents excluded volume per mole.
1️⃣6️⃣ Boyle temperature → Specific temperature where real gas obeys Boyle’s law.
1️⃣7️⃣ 1.863 → Z = PV/nRT; calculation gives ~1.863 (positive deviation).
1️⃣8️⃣ an²/V² → Corrects for intermolecular attractions in van der Waals equation.
1️⃣9️⃣Intermolecular attraction → a/V² term accounts for attractive forces.
2️⃣0️⃣ (P + a/V²) → Pressure correction term accounts for intermolecular forces.
2️⃣1️⃣ Remain constant → PV = constant is Boyle’s law, valid only at constant temperature.
2️⃣2️⃣ Doubled → KE ∝ T; doubling temperature doubles kinetic energy.
2️⃣3️⃣ Compressibility factor → PV/nRT = Z, measures deviation from ideal gas.
2️⃣4️⃣ 7.09 m³ → Volume per molecule = b/N.
2️⃣5️⃣ 226.085 kPa → Conversion factor: 1 psi = 6.892 kPa.
2️⃣6️⃣ Depression → Meteorological term for low-pressure system.
2️⃣7️⃣ High temperature → Increases KE, reduces intermolecular attractions.
2️⃣8️⃣ 2 mole → 44.8 L ÷ 22.4 L/mol = 2 mol.
2️⃣9️⃣ Diffusion → Random spreading of molecules.
3️⃣0️⃣ Effusion → Escape through tiny hole into vacuum.
3️⃣1️⃣Elastic → Kinetic Molecular Theory: collisions of ideal gas molecules are perfectly elastic.
3️⃣2️⃣Equal to 1 → At zero pressure, compressibility factor Z → 1 (ideal behavior).
3️⃣3️⃣Low temperature → Lower KE → stronger intermolecular attractions.
3️⃣4️⃣NH₃ → Polar molecule with hydrogen bonding, not London forces.
3️⃣5️⃣General gas law → Combines Boyle’s and Charles’s laws into one expression.
3️⃣6️⃣Dalton’s law → Total pressure = sum of partial pressures of non-reacting gases.
3️⃣7️⃣Dalton’s law → Respiration involves partial pressures of gases in lungs/blood.
3️⃣8️⃣159.6 mm Hg → Partial pressure of oxygen in air at sea level.
3️⃣9️⃣Aqueous tension → Pressure due to water vapour in a gas mixture.
4️⃣0️⃣Gay-Lussac’s law → Volumes of gases in reactions combine in simple whole number ratios.
4️⃣1️⃣Pressure → Density formula d = PM/RT; directly proportional to pressure.
4️⃣2️⃣Temperature → Density inversely proportional to T in d=PM/RT.
4️⃣3️⃣200 ml/s → Graham’s law: CH₄ diffuses twice as fast as SO₂.
4️⃣4️⃣150 mm Hg → Oxygen partial pressure at altitude ~150 mm Hg causes discomfort.
4️⃣5️⃣Bond length → Isotopes have same nuclear charge → identical bond length.
4️⃣6️⃣Ideal gases → PV/nRT = 1 always → horizontal line.
4️⃣7️⃣Temperature → M = dRT/P → directly proportional to T.
4️⃣8️⃣M.W = RTd/P → Standard formula for molar mass using density.
4️⃣9️⃣Pressure → M inversely proportional to P in M = dRT/P.
5️⃣0️⃣Krypton → Noble gases are monoatomic.
5️⃣1️⃣ None of them → No real gas is perfectly ideal; ideal gas is hypothetical.
5️⃣2️⃣ All of them → All existing gases are real.
5️⃣3️⃣ Real gas → Deviates from gas laws at certain T and P.
5️⃣4️⃣ Low T, high P → Stronger intermolecular forces → non-ideal behavior.
5️⃣5️⃣ Non-polar gases → Weaker forces → more ideal.
5️⃣6️⃣ Polar gases → Stronger forces → more non-ideal.
5️⃣7️⃣ van der Waals forces → Short-range attractions between molecules.
5️⃣8️⃣ Temporary forces → van der Waals forces develop under low T, high P.
5️⃣9️⃣ London forces → Temporary dipoles in non-polar molecules/inert gases.
6️⃣0️⃣ van der Waals forces → London forces are a type of van der Waals force.
6️⃣1️⃣ 127ºC & 1 atm → High T, low P → maximum molar volume.
6️⃣2️⃣ d = MP/RT → Standard density formula.
6️⃣3️⃣546 K → Doubling absolute temperature doubles volume at constant pressure.
6️⃣4️⃣ Quadruple → Doubling T doubles V; halving P doubles V again → 4×.
6️⃣5️⃣ 0ºC → 273 K corresponds to 0ºC.
6️⃣6️⃣ NH₃ > CO₂ > SO₂ > Cl₂ → Diffusion rate inversely proportional to molar mass.
6️⃣6️⃣ C₃H₈ and CO₂ → Both have molar mass 44 g/mol → same diffusion rate.
6️⃣8️⃣ C₄H₁₀ → Highest molar mass → slowest diffusion.
6️⃣9️⃣ All of them → R has multiple equivalent values in different units.
7️⃣0️⃣ C₂H₄ → Lowest molar mass → fastest diffusion.
7️⃣1️⃣1 → Compressibility factor Z = PV/nRT; for ideal gas Z = 1.
7️⃣2️⃣30 torr → Aqueous tension = moist – dry = 735 – 705.
7️⃣3️⃣1/16 → Diffusion rate ∝ 1/√M; ratio gives MA/MB = 1/16.
7️⃣4️⃣8:1 → H₂ diffuses faster; composition ratio = 8:1.
7️⃣5️⃣Average KE → KE depends only on T, same for all gases.
7️⃣6️⃣Same as before → V ∝ T/P; halving T and doubling P cancels out.
7️⃣7️⃣0.1 atm → 0.101325 bar ≈ 0.1 atm.
7️⃣8️⃣0.5 atm, 500 K → High T, low P → ideal behaviour.
7️⃣9️⃣Motion stops → At absolute zero, molecular motion ceases.
8️⃣0️⃣Isothermal → Boyle’s law applies at constant T.
8️⃣1️⃣4:1 → Diffusion rate ratio = √16/√1 = 4:1.
8️⃣2️⃣Force per unit area → Pressure definition.
8️⃣3️⃣14.7 psi → Standard atmospheric pressure.
8️⃣4️⃣–121.5°C → Volume halves when T halves (Charles’s law).
8️⃣5️⃣1.01325 × 10² kPa → Standard pressure = 1 atm = 101.325 kPa.
8️⃣6️⃣1/64 → Diffusion rate ratio gives MA/MB = 1/64.
8️⃣7️⃣87.5 kPa → Weighted average pressure after connection.
8️⃣8️⃣All of them → –273.15°C, –459.7°F, 0 K all represent absolute zero.
8️⃣9️⃣32 g → Graham’s law calculation gives molar mass = 32 g.
9️⃣0️⃣Half → V ∝ T/P; doubling T and quadrupling P halves volume.
9️⃣1️⃣Both b and c → Diffusion/effusion rates depend only on molar mass; same mass → same rates.
9️⃣2️⃣4 times → P ∝ T/V; doubling T and halving V quadruples pressure.
9️⃣3️⃣None of these → R is universal constant; depends only on chosen units.
9️⃣4️⃣Evaporation → Converts liquid to gas, weakening intermolecular forces.
9️⃣5️⃣4:1 → Graham’s law: H₂ diffuses 4× faster than O₂.
9️⃣6️⃣72 → Graham’s law calculation gives molar mass of X = 72 g/mol.
9️⃣7️⃣1.41 → D₂ diffuses √2 times slower than H₂.
9️⃣8️⃣Graham’s law → Basis for isotope separation (lighter diffuses faster).
9️⃣9️⃣LDF → London dispersion forces are weakest intermolecular forces.
1️⃣0️⃣0️⃣227ºC & 1 atm → High T and low P → maximum molar volume.

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MDCAT/ECAT/FSC Chapter-wise High-Yield Chemistry MCQs Quiz on Atomic Structure


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جونؔ ایلیا کے مشہور اشعار
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حال خوش تذکرہ نگاروں کا

تھا تو اک شہر خاکساروں کا

پہلے رہتے تھے کوچۂ دل میں

اب پتہ کیا ہے دل فگاروں کا

کوئے جاناں کی ناکہ بندی ہے

بسترا اب کہاں ہے یاروں کا

چلتا جاتا ہے سانس کا لشکر

کون پُرساں ہے یادگاروں کا

اپنے اندر گھسٹ رہا ہوں میں

مجھ سے کیا ذکر رہ گزاروں کا

ان سے جو شہر میں ہیں بے دعویٰ

عیش مت پوچھ دعویداروں کا

کیسا یہ معرکہ ہے برپا جو

نہ پیادوں کا نہ سواروں کا

بات تشبیہہ کی نہ کیجیو تُو

دہر ہے صرف استعاروں کا

میں تو خیر اپنی جان ہی سے گیا

کیا ہوا جانے جانثاروں کا

کچھ نہیں اب سوائے خاکستر 

ایک جلسہ تھا شعلہ خواروں کا

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ہر طنز کیا جائے ہر اک طعنہ دیا جائے
کچھ بھی ہو پر اب حد ادب میں نہ رہا جائے
تاریخ نے قوموں کو دیا ہے یہی پیغام
حق مانگنا توہین ہے حق چھین لیا جائے

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؎خلد گم گشتہ کا موضوع نہ چھیڑو کہ مجھے

اپنے خوں گشتہ خیالوں سے حجاب آتا ہے

یادِ ماضی سے میرے ذہن کو محفوظ رکھو

یاد ماضی نہیں آتی ہے عذاب آتا ہے


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لمحہ لمحہ پڑھا کرے انسان

نوحہ کل من علیہا فانٍ
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؎انکار ہے تو قیمت انکار کچھ بھی ہو

یزداں سے پوچھنا یہ ادا اہرمن میں تھی


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میں بھی بہت عجیب ہوں اتنا عجیب ہوں کہ بس

خود کو تباہ کر لیا اور ملال بھی نہیں

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جو گزاری نہ جا سکی ہم سے
ہم نے وہ زندگی گزاری ہے

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یہ مجھے چین کیوں نہیں پڑتا
ایک ہی شخص تھا جہان میں کیا
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کتنی دل کش ہو تم کتنا دلجو ہوں میں
کیا ستم ہے کہ ہم لوگ مر جائیں گے
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کون اس گھر کی دیکھ بھال کرے
روز اک چیز ٹوٹ جاتی ہے
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بہت نزدیک آتی جا رہی ہو
بچھڑنے کا ارادہ کر لیا کیا
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تو نے تو ہم سے آج تک کوئی گلہ نہیں کیا
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کیا کہا عشق جاودانی ہے!
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اس گلی نے یہ سن کے صبر کیا
جانے والے یہاں کے تھے ہی نہیں
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حاصل کن ہے یہ جہان خراب
یہی ممکن تھا اتنی عجلت میں
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اب جو رشتوں میں بندھا ہوں تو کھلا ہے مجھ پر
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آج بہت دن بعد میں اپنے کمرے تک آ نکلا تھا
جوں ہی دروازہ کھولا ہے اس کی خوشبو آئی ہے
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یہ وار کر گیا ہے پہلو سے کون مجھ پر
تھا میں ہی دائیں بائیں اور میں ہی درمیاں تھا

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ساری گلی سنسان پڑی تھی باد فنا کے پہرے میں
ہجر کے دالان اور آنگن میں بس اک سایہ زندہ تھا

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اک عجب آمد و شد ہے کہ نہ ماضی ہے نہ حال
جونؔ برپا کئی نسلوں کا سفر ہے مجھ میں

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حملہ ہے چار سو در و دیوار شہر کا
سب جنگلوں کو شہر کے اندر سمیٹ لو

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پہلے رہتے تھے کوچئہ دل میں

اب پتا کیا ہے دل فگاروں کا جونؔ


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جونؔ خطرہ ہے جان جانے کا

یہ جہاں جونؔ! اک جہنم ہے

یاں خدا بھے نہیں ہے آنے کا

زندگی ایک فن ہے لمحوں کا 
اپنے انداز سے گنوانے کا

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آج کے بعد عشرتِ مجلسِ شامِ غم کہاں

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نکہتِ یاسمین قبا بھول نہ جائیو ہمیں

صبح کے بعد تُو کہاں شام کے بعد ہم کہاں

یہ جو نواگری کے ساتھ چیخ نہیں رہا ہوں میں

سینہ نے نواز میں آخر اب اتنا دم کہاں

اب یہ جبین و چشم و لب تجھ کو نظر نہ آئیں گے

غور سے دیکھ لے ہمیں آج کے بعد ہم کہاں 
جونؔ ایلیا


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