Class 12 - Types of Organic Reactions – Chemistry Notes | Substitution, Addition, Elimination & Rearrangement Reactions

 Learn all Types of Organic Reactions in Class 12 Chemistry with clear examples — Substitution, Addition, Elimination, and Rearrangement reactions. Easy-to-understand notes for board exams, MDCAT, and NEET preparation.

Welcome to Learn Chemistry by Inam Jazbi!
In this article, we’ll discuss one of the most important topics from Class 12 Organic Chemistry — the Types of Organic Reactions. Organic reactions are classified based on how atoms or groups of atoms are replaced, added, removed, or rearranged in molecules.
Understanding these reaction types helps you predict reaction products and mechanisms in board exams and competitive tests like MDCAT and NEET.

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🔸 Main Types of Organic Reactions

Organic reactions can be broadly divided into four main types:

Type of ReactionDefinitionGeneral ExampleExplanation
1. Substitution ReactionA reaction in which one atom or group of atoms in a molecule is replaced by another atom or group.CH₃Cl + OH⁻ → CH₃OH + Cl⁻The Cl atom is substituted by the OH group.
2. Addition Reaction

A reaction in which two or more reactants combine to form a single product (usually occurs in unsaturated compounds like alkenes or alkynes).
C₂H₄ + H₂ → C₂H₆Hydrogen adds to the double bond of ethene.
3. Elimination Reaction

A reaction in which a small molecule is removed from a larger molecule, resulting in the formation of a double or triple bond.
C₂H₅Br → C₂H₄ + HBrHydrogen bromide is eliminated to form ethene.
4. Rearrangement Reaction

A reaction in which the structure of a molecule changes due to the rearrangement of atoms or groups within the molecule.
CH₃–CH₂–OH → CH₃–O–CH₂HThe atoms rearrange to form a new structure.

🔹 Additional Types (for Advanced Study)

  • Oxidation Reactions: Addition of oxygen or removal of hydrogen (e.g. alcohol → aldehyde).

  • Reduction Reactions: Addition of hydrogen or removal of oxygen (e.g. alkene → alkane).

  • Condensation Reactions: Two molecules combine with the elimination of a small molecule (like water).


🧠 Quick Summary

Reaction TypeMain ProcessExample
SubstitutionReplacementCH₃Cl + NaOH → CH₃OH
AdditionCombinationC₂H₄ + Br₂ → C₂H₄Br₂
EliminationRemovalC₂H₅OH → C₂H₄ + H₂O
RearrangementStructural shiftCH₃–CH₂–OH → CH₃–O–CH₂H




















































































































































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