Answer
Atomic Mass Unit (amu)
One twelfth
(1/12) of the mass of one atom of carbon-12 is termed as Atomic Mass Unit
abbreviated as a.m.u. i.e. 1
a.m.u. = 1/2th weight of carbon-12 = 1.66 x 10–24 g
Molecular Mass
It is the
average mass of a molecule of a substance (element or compound) as compared
with 1/12th mass of one atom of C-12. molecular Formula mass or Molecular Mass of a substance is
the sum of atomic masses of all atoms present in a molecule of a substance shown
by its molecular formula.
Formula Mass
Formula mass of a substance (ionic
compounds) is the sum of atomic masses of all atoms in formula unit shown by
its simplest or empirical formula.
Gram Atomic Mass
The atomic mass of an element expressed in gram is called gram
atomic mass. It is also called 1 mole.
Gram Molecular Mass
The molecular mass of an element or a compound expressed in gram is
called gram molecular mass. It is also called 1 mole.
Gram Formula Mass
The formula mass of an ionic compound expressed in grams is called
gram formula mass. It is also called 1 mole.
Molar Mass
The relative atomic mass or molecular
mass or formula mass of a substance expressed in gram is called its molar mass.
The unit of molar mass is gram/mol.
Mole
Mole is the S.I. base unit of chemical
amount of substance. A mole of a substance can be defined as the atomic
mass or molecular mass or formula mass of a substance (element or compound)
expressed in gram containing 6.02 x 1023 particles (Atoms, molecules
or ions)”.
Avogadro’s
number
The number
of elementary particles (atoms, molecules, ions or formula units) contained in
one mole of a substance (element or
compound) is found to be 6.02 x 1023 called Avogadro’s number. It is
denoted as NA.
Molar Gas
Volume or Molar Volume (VM)
According to Avogadro, one gram mole of any gas at STP occupies
volume of 22.4 dm3 (where standard temperature is OOC and
standard pressure is 1 atm). The volume
occupied by one mole of any gas at s.t.p
is 22.4 dm3 (Litre) and is referred to as Molar Volume.
1
mole of a gas at S.T.P = 22.4 dm3 mol-1
Difference between Atomic and Molecular Mass
Difference between Gram atom and Gram Molecule
Difference between Molecular and Formula Mass
Difference between Empirical and Molecular Formula
Q20. Calculate the
formula mass (a.m.u) of the following
Solution
Q21. Calculate molecular (a.m.u) of the
following
Solution
Calculation of number of moles in 53 g of
Na2CO3
Given mass of Na2CO3 (ionic compound) =
50 g
Molar mass of Na2CO3 (ionic compound) =
2 x23 + 1 x 12 + 3 x 16 = 106 g/mol
No. of moles of Na2CO3 = ?
No. of moles (n) = mass of substance in gram/molar mass of
substance
=
53/106 = 0.5 mole
Calculation of number of moles in 36 g of
H2O
Given mass of H2O (Molecular compound) = 36 g
Molar mass of H2O = 2 x1 + 1 x 16 = 18 g/mol
No. of moles of H2O = ?
No. of moles (n) = mass of substance in gram/molar mass of
substance
=
36/18 = 2.0 mole
Solution
Calculation of Mass of 1 atom of carbon
Calculation of Mass of 1 molecule of
water
Q9. Calculate the number of atoms present in 2.3 g of sodium (Na)
Solution
Q10. A coin of silver (Ag) having 8.5 g weight. Calculate the number of moles and number of atoms of silver in coin?
Solution
Calculation of number of moles in 8.5 g
of silver
Given mass of silver = 8.5 g
Molar mass of silver = 108 g/mol
No. of moles (n) = mass of substance in gram/molar mass of
substance
=
8.5/108 = 0.0787 mole
Calculation of number of atoms in 8.5 g of silver
Number of atoms = number of moles x
Avogadro’s number
Number of atoms = 0.0787 x 6.02 x
1023
Number of
atoms = 0.473 x 1023 = 4.73 x 1022 atoms
Q11. Calculate number of mole in 900 g of glucose.
Solution
Calculation of number of moles in 900 g
of glucose
Given mass of C6H12O6 = 900 g
Molar mass of C6H12O6 = 6 x
12 + 12 x 1 + 6 x 16 = 180 g/mol
No. of moles (n) = mass of substance in gram/molar mass of
substance
=
900/180 = 5 mole
Solution
Calculation of number of moles in 8 g of
glucose
Given mass of C6H12O6 = 8 g
Molar mass of C6H12O6 = 6 x 12 + 12 x 1 + 6 x 16 = 180 g/mol
No. of moles (n) = mass of substance in gram/molar mass of
substance
=
8/180 = 0.04 mole
Calculation of number of molecules in 8 g
of glucose
No. of particles = no. of moles x
Avogadro’s number
= 0.04 x 6.02 x 1023 = 2.67 x x 1022
Q11. How many liters of carbon dioxide would
be produced if 0.450 of a mole of carbon monoxide reacts with excess oxygen at
STP. (answer;10.08 liter of Co2)
Q8. Calculate
the number of moles, number of molecules and number of atoms present in 10 g H2SO4?
Solution
Given
Mass of H2SO4
= 10 g
Molar mass
of H2SO4 = 2(1) + 32 + 4(16) = 98 g/mol
Avogadro’s
number = 6.02 x 1023
Atomicity of
H2SO4 = 2+1+4 =7
Required
No. of moles
= ?
No. of
molecules = ?
No. of atoms
= ?
Calculating
No. of Moles of H2SO4
No. of moles
(n) = mass of substance/molar mass = 10/98 = 0.1
mol
Calculating
No. of Molecules of H2SO4
No. of moles
(n) = no. of particles/Avogadro’s no (NA)
No. of
particles (molecules) = n x NA = 0.1 x 6.02 x 1023 = 6.02 x 1022 Molecules
Calculating
No. of atoms of H2SO4
No. of atoms
= no. of molecules x atomicity = 6.02 x 1022 x 7 = 4.214 x 1023 atoms
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