M.C.Qs on Chemical Bonding ...... Unit # 6


Unit # 6…….. M.C.Qs  on Chemical Bonding 

1.         The shell of an atom with highest ‘n’ is known as:
(a)
Valance shell
(b)
Inner shell
(c)
Empty shell
(d)
Filled shell.

2.         All inert gases except Helium are characterized by a completion of the outer ………
(a)
s-orbital
(b)
p-orbital
(c)
d-orbital
(d)
f-orbital

3.         Neutral atoms of Neon have the same number of electrons as each of the following:
(a)
O2–
(b)
F1–
(c)
Na1+
(d)
Mg2+

4.         The attractive forces that holds an atom together in a molecule is termed as:
(a)
Covalent bond
(b)
Dative bond
(c)
Chemical bond.
(d)
Ionic bond

5.         Chemical bond formation takes place due to interaction of …………electrons.
(a)
Valance
(b)
Inner
(c)
Free
(d)
Paired

6.         Lower the energy…………. will be stability of molecules.
(a)
Lesser
(b)
Greater
(c)
Both a and b
(d)
None of the above

7.         Inert gases have ……………….valance electrons.
(a)
5
(b)
4
(c)
7
(d)
8

8.         Which of the compounds have the ionic bond?
(a)
NaCl
(b)
KCl
(c)
MgO
(d)
All of the above

9.         The mutual sharing of electrons pairs in atoms gives rise to:
(a)
Hydrogen bond
(b)
Ionic bond
(c)
Covalent bond
(d)
Dative bond

10.     Which molecule has covalent bond?
(a)
NaCl
(b)
CaCO3
(c)
MgO
(d)
HCl

11.       the bond formed by mutual sharing of one electron pair b/w two bonded atoms is called…… bond:
(a)
Single covalent
(b)
Double covalent
(c)
Triple covalent
(d)
Ionic bond

12.     Which molecule has single covalent bond?
(a)
O2
(b)
N2
(c)
CO2
(d)
CH4

13.     which molecule does not have single covalent bond?
(a)
O2
(b)
N2
(c)
CCl4
(d)
HF

14.     Which molecule has double covalent bond?
(a)
O2
(b)
N2
(c)
CCl4
(d)
HF

15.     Which molecule has triple covalent bond?
(a)
O2
(b)
N2
(c)
CCl4 or CH4
(d)
H2

16.     Bond making is always:
(a)
Endothermic
(b)
Exothermic
(c)
Both a and b
(d)
None of the above
17.       Bond breaking is always:
(a)
Endothermic
(b)
Exothermic
(c)
Both a and b
(d)
None of the above

18.     The formation of chemical bond is accomplished by:
(a)
Decrease in energy
(b)
Increase in energy
(c)
Neither decrease nor increase in energy
(d)
The repulsive forces overcoming the attractive forces

19.     chemical bond formation takes place when:
(a)
Forces of repulsions overcome forces of attractions.
(b)
Energy is absorbed
(c)
Forces of attractions are equal to forces of repulsions
(d)
Forces of attractions overcome forces of repulsions

20.       Which one is correct reading ionic bond?
(a)
It is formed by complete transference of electrons from one atom to another.
(b)
It is an electrostatic force of attraction b/w two oppositely charged ions.
(c)
It is formed b/w atoms of low IP and atoms of high EM
(d)
All of the above

21.       Generally an ionic bond is formed b/w:
(a)
Elements of group IA an IIA and elements of group VIA and VIIA.
(b)
Elements of group VA an VIIA.
(c)
Elements of group IA an VIIA.
(d)
None of the above.

22.       In which one of the following does ionic bonding occur between named atoms?
(a)
Aluminium and chlorine in the tetrachloroaluminate ion.
(b)
Boron and fluorine in boron trifluoride.
(c)
Hydrogen and chlorine in hydrogen chloride.
(d)
Hydrogen and sodium in sodium hydride.

23.       Which one is correct reading ionic bond and Ionic compounds?
(a)
Ionic bond is non directional
(b)
Ionic compounds are non-electrolytes and volatile
(c)
Ionic compounds are hard and rigid solid
(d)
Ionic compounds are soluble in polar solvent

24.       Which one is correct reading covalent bond and covalent compounds?
(a)
covalent bond is directional.
(b)
Covalent compounds are non-electrolytes and volatile.
(c)
covalent compounds are soft and brittle.
(d)
Covalent compounds are usually soluble in non-polar solvent.

25.     Which one is correct reading the effect of  ionic character of covalent bond on the properties           of compounds?
(a)
Its elevates m.p and b.p
(b)
It increases the stability of compounds in polar solvent (H2O)
(c)
It shorten the bond distance thereby enhancing bond energies
(d)
All of the above.

26.       Which one is incorrect reading bond energy?
(a)
It is the amount of energy required to break one mole of bond to form isolated natural atom.
(b)
It measures the strength of covalent bond.
(c)
It increases with the increase in polarity.
(d)
Bond energy of non-polar molecule is greater then that of polar molecule.

27.       Which one has highest bond energy?
(a)
Non- Polar molecule
(c)
Polar compounds having multiple bond
(b)
Polar compounds having single bond
(d)
None of the above.

28.       A covalent bond in which the shared electron pair is attracted equally by the two atoms is called:
(a)
Polar bond
(b)
Non- Polar bond
(c)
dative bond
(d)
hydrogen bond
29.       Which one is correct reading the examples of Non- Polar bond?
(a)
S=C=S
(b)
PH3
(c)
CH4
(d)
CH3Cl

30.       A covalent bond in which the shared electron pair is attracted equally by the two atoms is called:
(a)
Polar bond
(b)
Non- Polar bond
(c)
dative bond
(d)
hydrogen bond

31.     Which molecule has greater bond energy?
(a)
Polar molecule
(b)
Non- Polar molecule
(c)
None of the above
(d)
All of the above.

32.     Greater the difference in E N b/w bonded atoms _________will be polarity.
(a)
Lesser
(b)
Greater
(c)
None of the above
(d)
All of the above.

33.     A bond is said to be 100% covalent, if it exists b/w atoms of:
(a)
Same elements
(b)
Different elements
(c)
Same group
(d)
Different group

34.     The one sided sharing of electrons b/w two atoms produces which type of bond?
(a)
covalent bond
(b)
hydrogen bond
(c)
dative bond
(d)
Ionic bond

35.     Which of the following has co-ordinate covalent bond?
(a)
NH4+
(b)
H2O
(c)
H3O+
(d)
Both a and c

36.       Which of the following has the shortest C─C bond length?
(a)
C2H2
(b)
C2H4
(c)
C2H6
(d)
C2H5OH

37.     Which of the following has the highest bond energy?
(a)
C2H2
(b)
C2H4
(c)
C2H6
(d)
C2H5OH

38.     Which one of the following bond has the most polar character?
(a)
C–O
(b)
C–Br
(c)
C–F
(d)
C–S

39.     Which one of the following bond has the least polar character?
(a)
C–H
(b)
C–Cl
(c)
C–O
(d)
C–N

40.     the degree or extent of polarity of a molecule is called:
(a)
Bond energy
(b)
Moment arm
(c)
Dipole moment
(d)
Ionic character

41.     the product of magnitude of charge at each pole and the internuclear distance b/w the two    opposite charges called:
(a)
debye
(b)
Moment arm
(c)
Dipole moment
(d)
Bond length

42.       Dipole moment is a:
(a)
Scalar quantity
(b)
Vector quantity
(c)
Basic quantity
(d)
None of the above

43.     Dipole moment is denoted by:
(a)
Double head arrow
(b)
Double arrow
(c)
Crossed tail arrow
(d)
None of the above

44.     dipole moment is defined as
(a)
Charge x Internuclear distance
(b)
Charge x Charge
(c)
Charge x Debye
(d)
Charge x Bond energy
45.     S.I unit of dipole moment (µ) is
(a)
N-sec
(b)
N.m2
(c)
C.m (coulomb x meter)
(d)
None of the above

46.       1 coulomb is equal to:
(a)
2.99x10-9 e.s.u
(b)
2.99x1019 e.s.u
(c)
2.99x10-19 e.s.u
(d)
None of the above

47.     1 debye (1D) is equal to:
(a)
10-30 coulomb-meter
(b)
10-18 e.s.u-cm
(c)
10-10 e.s.u-m
(d)
All of the above

48.       the diatomic polar molecules have dipole moment:
(a)
Equal to 0
(b)
Greater than 0
(c)
Equal to 1
(d)
None of the above

49.       Which one has zero dipole moment?
(a)
CO2
(b)
CS2  
(c)
HCl
(d)
Both a and b

50.     CO2 and CS2 has no dipole moment due to:
(a)
Linear structure
(b)
Angular structure
(c)
Pyramidal structure
(d)
Both a and b

51.     H2O and SO2 have dipole moment:
(a)
Equal to 0
(b)
Greater than 0
(c)
Equal to 1
(d)
None of the above

52.     H2O and SO2 have same dipole moment due to its:
(a)
Bent structure
(b)
Angular structure
(c)
Both a and b
(d)
None of the above

53.       the structure of triatomic molecule whose dipole moment is zero will be:
(a)
Linear structure
(b)
Angular structure
(c)
Pyramidal structure
(d)
Tetrahedral

54.     tetrahedral molecules with symmetric structure have
(a)
Zero dipole moment
(b)
Some dipole moment
(c)
Both a and b
(d)
None of the above

55.       CH4 and CCl4 have zero dipole moment due to:
(a)
Symmetrical structure
(b)
Unsymmetrical structure
(c)
Both a and b
(d)
None of the above

56.       tetrahedral  molecules with unsymmetrical structures have 
(a)
Zero dipole moment
(b)
Some dipole moment
(c)
Both a and b
(d)
None of the above

57.       CH3Cl,CH2Cl2 and CHCl3 have some dipole moment due to
(a)
Symmetrical structure
(b)
Unsymmetrical (or Asymmetrical) structure
(c)
Both a and b
(d)
None of the above

58.       the bond energy of hydrogen bond ranges
(a)
3 – 10 kcal
(b)
10 – 17 kcal
(c)
17 – 25 kcal
(d)
25-35 kcal

59.       water boils at higher temperature than H2S due to
(a)
Ionic bonding
(b)
Covalent bonding
(c)
London forces
(d)
Hydrogen bonding

60.       hydrogen bond greatly ……………… the solubility of compound
(a)
Increase
(b)
Decrease
(c)
Has no effect
(d)
Both a and b

61.       Ethyl alcohol is liquid while its isomer dimethyl ether is gas. This is b/c ethyl alcohol has
(a)
Ionic bonding
(b)
Covalent bonding
(c)
Protonic Bridges
(d)
London forces

62.       hydrogen bond ……………. the m.p and b.p of compounds.
(a)
Elevates
(b)
Reduces
(c)
Has no effect of
(d)
Both a and b

Modern Concept of Covalent Bonding

63.       the modern theories of covalent bond is
(a)
Valance Bond Theory (VBT)
(b)
Molecular Orbital theory(MOT)
(c)
Valance shell electron pair repulsion (VSEPR) theory
(d)
All of the above.

64.       which theory explain the chemical bonding in terms of overlapping of atomic orbitals which retain their identities and share electrons is mono centric
(a)
VBT
(b)
MOT
(c)
VSEPR
(d)
All of the above

65.       the molecular orbitals which have lower energy then parent atomic orbital are called
(a)
Bonding molecular orbital(BMO)
(b)
Antibonding molecular orbital          (AMO)
(c)
Both a and b
(d)
None of the above

66.       the molecular orbitals which have higher energy than parent atomic orbital are called
(a)
AMO
(b)
BMO
(c)
Hybrid orbital
(d)
All of the above

67.       a bond formed by the pairing of electrons spin caused by the axial overlapping of half filled atoms is called
(a)
Sigma bond       
(b)
Pi bond
(c)
Ionic bond
(d)
None of the above

68.     in a sigma bond the region of …….. electron density is symmetrically distributed around axis
(a)
Lowest      
(b)
Intermediate
(c)
Highest
(d)
All of the above.

69.     sigma bond has
(a)
Lowest      
(b)
Intermediate
(c)
Highest
(d)
All of the above.

70.     which bond is more stable?
(a)
Sigma bond       
(b)
Pi bond
(c)
Both a and b
(d)
None of the above

71.     How many sigma bonds can be predicted between two atoms?
(a)
4      
(b)
3
(c)
2
(d)
1

72.     in hydrogen molecule sigma bond is formed by the head on overlapping of half filled
(a)
p-p orbitals         
(b)
s-s orbitals
(c)
d-d orbitals
(d)
f-f orbitals

73.     in F2 molecule sigma bond is formed by the end to end overlapping of half filled
(a)
p-p orbitals         
(b)
s-s orbitals
(c)
d-d orbitals
(d)
f-f orbitals

74.     in HCl molecule sigma bond is formed by the axial overlapping of half filled
(a)
s-p orbitals
(b)
s-s orbitals
(c)
d-d orbitals
(d)
s-p3 orbitals

75.     in CH4 molecule a sigma bond is formed by the axial overlapping half filled
(a)
p-p orbitals         
(b)
s-s orbitals
(c)
d-d orbitals
(d)
s-sp3 orbitals
76.     in C2H4 molecule a sigma bond between C to C is formed by the axial overlapping half filled
(a)
s-p orbitals
(b)
s-s orbitals
(c)
s-p orbitals
(d)
sp2-sp2 orbitals

77.     a bond formed by pairing of electron spin caused by the parallel or side wise overlapping of      two half filled coplanar p-atomic orbitals already bonded through a sigma bond is called
(a)
Sigma bond       
(b)
Pi bond
(c)
Hydrogen bond
(d)
None of the above

78.     pi-bond is formed by the overlap of
(a)
p-p orbitals
(b)
s-s orbitals
(c)
s-p orbitals
(d)
sp3-sp3 orbitals

79.     the process of mixing different atomic orbitals having small energy difference and different         shapes belonging to the same atoms to form an equal no of new set of equivalent orbitals of          the same energy, size and shape is called
(a)
Overlapping       
(b)
Hybridization
(c)
Blending
(d)
Delocalization

80.     the hybrid orbitals are …………orbitals.
(a)
Atomic      
(b)
Molecular
(c)
Both a and b
(d)
None of the above

81.     the process of mixing of one s and three p orbitals of the same atom to form four new       equivalent hybrid orbital is called
(a)
sp hybridization
(b)
sp3 hybridization
(c)
sp2 hybridization
(d)
None of the above

82.     in sp3 hybrid orbitals the ratio of s and p orbitals is
(a)
1:2
(b)
1:3
(c)
1:4
(d)
1:1

83.     the angel between sp3 hybrid orbitals is
(a)
180o
(b)
120o
(c)
104.5o
(d)
109.5o

84.     which of the following hybrid orbitals has 25% s character and 75% p character
(a)
sp3
(b)
sp2
(c)
sp
(d)
None of the above

85.     in which molecule carbon atom is sp3 hybridized
(a)
C2H2
(b)
C2H4
(c)
CH4
(d)
C6H6

86.     the process of mixing of one s and two p orbitals of the same atom to form three new     equivalent hybrid orbital is called
(a)
sp3
(b)
sp2
(c)
sp
(d)
None of the above

87.       in sp2 hybrid orbitals the ratio of s and p orbitals is
(a)
1:2
(b)
1:3
(c)
1:4
(d)
1:1

88.     the angel between sp2 hybrid orbitals is
(a)
180o
(b)
120o
(c)
104.5o
(d)
109.5o

89.     which of the following hybrid orbitals has 33.33% s character and 66.66% p character
(a)
sp3
(b)
sp2
(c)
sp
(d)
None of the above

90.     in which molecule carbon atom is sp2 hybridized
(a)
C2H4
(b)
C6H6
(c)
C2H6
(d)
Both a and b

91.     the process of mixing of one s and one  p orbitals of the same atom to form two new        equivalent hybrid orbitals is called
(a)
sp3
(b)
sp2
(c)
sp
(d)
None of the above

92.     in sp1 hybrid orbitals the ratio of s and p orbitals is
(a)
1:2
(b)
1:3
(c)
1:4
(d)
1:1

93.     the angel between sp3 hybrid orbitals is
(a)
180o
(b)
120o
(c)
104.5o
(d)
109.5o

94.     which of the following hybrid orbitals has 50% s character and 50% p character?
(a)
sp3
(b)
sp2
(c)
sp
(d)
None of the above

95.     in which molecule carbon atom is sp hybridized
(a)
C2H4
(b)
C6H6
(c)
C2H6
(d)
C2H2

96.     a molecule of ethylene (C2H4) contains total
(a)
2 σ and 1 π bond
(b)
5 σ and 1 π bond
(c)
4 σ and 2 π bond
(d)
3 σ and 3 1π bond

97.     a molecule of acetylene (C2H2) contains total
(a)
3 σ and 2 π bond
(b)
2 σ and 3 π bond
(c)
4 σ and 1 π bond
(d)
5 σ and no π bond

98.     a molecule of ethane (C2H6) contains total
(a)
7 σ and 1 π bond
(b)
6 σ and no π bond
(c)
5 σ and no π bond
(d)
7 σ and no π bond

99.     The active electrons pair around the central atom are arranged in space in such a way that    they keep as far a part as possible so that there is minimum inter-electronic repulsion. This     is the basic assumption of
(a)
MOT
(b)
VBT
(c)
VSLPR theory
(d)
H.O.M

100.      inter-electronic repulsion forces decrease sharply with increasing
(a)
Bond length
(b)
Bond energy
(c)
Bond angle
(d)
All of the above.

101.     the presence of lone pair on the central atom ………… bond angle
(a)
Expend
(b)
Contract
(c)
Has no effect on
(d)
All of the above.

102.      two active pairs of electron in valance shell around the central atom will give
(a)
Linear shape
(b)
Angular
(c)
Trigonal
(d)
Pyramidal

103.     which one has linear structure?
(a)
BeCl2
(b)
CO2 or CS2
(c)
C2H2
(d)
All of the above.

104.      three active pairs of electron in valance shell around the central atom will give shape
(a)
Linear shape
(b)
Angular
(c)
Trigonal
(d)
Pyramidal

105.    which of the following has trigonal shape?
(a)
BCl3
(b)
C2H4
(c)
SO3  or CO42–   
(d)
All of the above

106.    four active pairs of electron in valance shell around the central atom with no non-bonding    (lone pair) electrons will give …………….shape
(a)
Tetrahedral
(b)
Angular
(c)
Trigonal
(d)
Pyramidal

107.    which of the following has tetrahedral shape?
(a)
CH4
(b)
CCl4
(c)
C2H6
(d)
SO42–

108.  Four active pairs of electron in valance shell around the central atom with one non-bonding (lone pair) electrons will give …………….. shape
(a)
Tetrahedral
(b)
Angular
(c)
Trigonal
(d)
Pyramidal

109.              which of the following has pyramidal shape?
(a)
NH3 or PH3
(b)
CO
(c)
H2O
(d)
Both a and b

110.  four active pairs of electron in valance shell around the central atom with two non-bonding (lone pair) electrons will give …………… shape
(a)
Tetrahedral
(b)
Angular
(c)
Trigonal
(d)
Pyramidal

111.      which of the following has angular shape?
(a)
H2O or H2S
(b)
SO2
(c)
SCl2
(d)
All of the above.

112.      the bond angle in NH3 (Pyramidal molecule) is
(a)
180o
(b)
120o
(c)
107o
(d)
109.5o

113.     the bond angle in H2O (Angular molecule) is
(a)
180o
(b)
120o
(c)
107o
(d)
104.5o

114.      all diatomic molecules are _____________ in shape
(a)
Tetrahedral
(b)
Angular
(c)
Planar Trigonal
(d)
Linear

115.     the shape of HCl, HBr, HF and HI are
(a)
Tetrahedral
(b)
Angular
(c)
Planar Trigonal
(d)
Linear

116.      the shape of NH2Cl2 molecule is
(a)
Tetrahedral
(b)
Angular
(c)
Planar Trigonal
(d)
Linear

117.    the shape of NHCl3 molecule is
(a)
Tetrahedral
(b)
Angular
(c)
Planar Trigonal
(d)
Linear












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