Total marks: 60
Time:
3 Hours
General Instructions
Section – A; contains 12 MCQs and all of them are to be answered.
Section – B; consists of 12 short-answer questions of which 8 are to be answered (24 marks)
Section – C; consists of 6 Long-answer questions of which 4 are to be answered (24marks)
Q1. Define any
three of the following:
Valency,
Electronegativity, electron affinity, Tyndall effect, free radical, molecular
ion, mole, molar volume, empirical and molecular formula, Molarity, concentration, false
solution, mass/volume percent, Freezing Point, absolute
zero, allotropy, Dobereiner’s
law of Triads, Newland’s law of Octaves, Mendeleev’s Periodic law, Periodicity, periodic trend, modern, periodic
law
Q2. Write down
three differences between any one of the following:
(i) Alkali metal and halogens
(ii) Ionic, covalent bond
and dative bond
(iii) elements, compounds and mixtures
(iv) Ionic compounds and covalent compounds
(v) Solution, suspension and Colloid
(vi) metal, metals and metalloids
(vii) Atom and molecule and ion
(viii) Molecule and molecular ion and free radical
Q3. What is meant by
atomic number and mass number. Define and give uses of isotopes. Discuss the isotopes of Hydrogen or carbon or uranium.
Mention the number of electrons, protons and neutrons in following atoms:
OR
Differentiate between EF and MF. Describe
relationship between empirical and molecular formula? Find out molecular formula of a compound if its
empirical formula is CH2O and molecular mass 60 amu. Complete
the following chart:
Q4. Identify group
and period in the periodic table of the following elements
(i) 3Li or 8O or 15P
(ii) 9F or 11Na and 17Cl
(iii) 12Mg or 13 Al or 14Si
OR
An element has 7 (or 1 or 2 or 8)
electrons in its M-shell. Answer the following questions:
(i) Determine its atomic number and give its Electronic configuration.
(ii) Identify the group, period and block of given
element.
(iii)
Write down three characteristics of the
belonging group. Also Write down the name and symbol
of radioactive element of this group.
Q5. Compare of reactivity of Alkali and Alkaline Earth Metals
OR
Write down one contribution of any 10 scientists in the field of chemistry. OR write down three significant reasons to study chemistry.
OR
Explain the
importance of glues and epoxy resins in our society.
Q6. Write chemical
formulae of any three of the following compounds:
Sand
(SiO2), Limestone (CaCO3) ,Sodium nitrate (NaNO3), table salt (NaCl), sal ammoniac (NH4Cl), Caustic soda (NaOH),
caustic potash (KOH), washing soda (Na2CO3.10H2O), baking soda (NaHCO3), soda ash (Na2CO3), Epsom salt
(MgSO4.7H2O),gypsum (CaSO4.2H2O), oleum (H2S2O7), marsh gas (CH4), blue vitriol (CuSO4.5H2O), sugar (C12H22O11), ethyl alcohol, Acetylene,
Ethylene,.
OR
What is coordinate
covalent bond? Explain with two examples.
Q7. Write down any
three points of atomic model proposed by Schrodinger or Bohr.
Or
Describe
wave particle duality of electron of De Broglie Hypothesis? Prove that modern
theory of De Broglie is related
with Einstein and Plank's equations.
Q8. Write down electronic configuration of 5B, 9F,
7N, 11Na, 15P, 20Ca, 19K+,
8O2−, 16S2−, 12Mg2+,
17Cl−.
OR
Justify that
Rutherford atomic model has defects? What are
Limitations of Bohr's Atomic Model?
Q9. Balance the
any three of the following chemical equations:
2KClO3 → 2KCl + 3O2
2Ba(NO3)2
→ 2BaO +
4NO2 + O2
2Na + 2H2O → 2NaOH + H2
2NH3
+ 3Cl2 → N2 + 6HCl
MnO2
+ 4HCl → MnCl2 + 2H2O
+ Cl2
4NH3 + 5O2 → 4NO + 6H2O
4Zn
+ 10HNO3 → 3H2O+ NH4NO3 +
4Zn(NO3)2
3CuO + 2NH3 → 3Cu + N2
+ 3H2O
OR
How is electronegative value
determined the formation of chemical bond? Describe ionic character in covalent
bond.
Q10. What is KMT? Give its main postulates with respect to three states
of matter.
OR
What is diffusion and Graham’s law
of diffusion of gases? Which gas from among CO2, CH4 and
NH3 will diffuse the
fastest and why? Give the reason.
Q11. Differentiate between amorphous and
Crystalline Solids?
OR
Explain
the solute-solvent interaction to prepare sodium chloride solution.
Q12.Define electrochemical reaction. Write down 2
differences between oxidation and reduction and oxidizing agent and reducing agent with
examples. Identify oxidizing and reducing agents of the following chemical reaction:
Zn
+ Cl2 → ZnCl2
OR
Differentiate
between electrolytes and non-electrolytes with examples. Identify strong and weak
electrolytes from the following:
HCl (S),
KI (S), NaOH (S), H2S (W), CH3COOH (W), NH4OH
(W), NaCl (S), C2H5OH (W)
Q13.
What is corrosion of metal and rusting?
Name the methods which are used to protect metal from corrosion. How cathodic protection prevent metal from
corrosion?
OR
Write down the composition of
following alloys:
Brass (Cu-Zn,[4:1]), Bronze
(Cu-Sn-Zn) [9:1], Bell metal (Cu-Sn), Monel (Ni-Cu-Fe), Amalgam (Hg-Ag-Cu-Zn), Pewter (Sn-Cu-Pb-Sb-Bi), White
gold (Au-Pb-Ag-Cu (18 karat), Duralumin (Al-Cu-Mg-Ni)
Q14. What are
metalloids? Write names and symbols of any 5 metalloids.
OR
Write names and symbols of some
noble metals. Explain inertness of noble metals.
OR
Define Moh Scale. What are Soft &
Hard Metals? Differentiate
between sodium and iron as soft and hard metal.
Q15. What is the
boiling point? How boiling point is affected by different factors? How boiling
point of a substance is affected
by atmospheric pressure?
Q16. What is
density, how the density of liquid is affected by temperature and pressure?
OR
What is
plasma? Explain plasma with the daily life examples?
Q17. Describe the construction of electrochemical cell. Write down names of
two types of electrochemical cells. Write
down 4 applications of electrolytic cells or electrolysis.
Q18. Give reason:
(i)
Why gasoline does not dissolve in water?
(ii)
Alkali metals are not found in free state in nature, why?
(iii)
Why ionic compounds conduct electricity in molten or in aqueous solutions only?
(iv)
Why the solubility of a salt increases with the increase in temperature?
(v)
Explain why table salt has a very high melting point.
(vi)
Atomic radii increases down a group and decrease across a period.
(vii)
Alkali metals have the largest while halogens have the smallest atomic radii in
their period.
(viii)
Shielding effect of inner electrons remains the same across a period.
(ix)
Ionization energy, electron affinity and electronegativity show same trends
across a period.
(x)
Covalent bonds are strong and hard to break but why most of the covalent
compounds have low melting and
boiling points.
19. Discuss Rutherford’s
Alpha particles scattering experiment & write down the postulates of his
atomic model.
OR
Determine
the demarcation of periodic table in to s, p, d and f blocks.
20. Define ionic bond. Discuss the formation of sodium chloride (NaCl).
OR
What
is meant by covalent bond and coordinate covalent bond? Describe
the formation of a covalent bond between
two nonmetallic atoms. Explain single, double and triple covalent bond with
examples. Explain dative bond with two
examples.
21. Describe
the Boyle's law or Charles's law with example.
OR
Define
vapour pressure. How equilibrium state involved in vapour pressure of liquids
in close system? Describe the factors
which affect on vapour pressure
22. Define the term
solubility. How does nature of solute and solvent determine the extent of
dissolution? Why the solubility of a salt
increases with the increase in temperature?
OR
Discuss
discharge tube experiment for the discovery of electrons with 4 properties of
cathode rays.
23. State
and explain Faraday’s Laws of electrolysis.
OR
What is
electroplating? How steel object can be electroplated with zinc and silver?
25. Explain electronegative character of non-metals or
electropositive character of metals. Discuss the reactivity of Halogens
OR
What are transition elements? Give
their types. Give their 4 general properties.
26. Explain the experiment to test CO32‒, Cl‒ and I‒ ions and Zn2+,
Mg2+, Ca2+ and Ba2+ ions.
Numericals
25. Calculate
the number of moles, number of molecules present in 8g of C6H12O6?
(answer; 0.04, 2.40 x 1022 molecules)
OR
Calculate the number of moles, number of molecules and number of atoms present in 10 g of H2SO4
(answer; 0.10 mole, 6.02 x 101022, 4.214 x 1023 atoms)
26. What is
the mass of oxalic acid (C2H2O4) required to
prepare 100 cm3 volume of 2M oxalic acid solution?
Or
What is the
molarity of the solution prepared by dissolving 1.25 g of HCl gas into enough
water to make 30 cm3
of solution?
27. Determine the
percentage concentration of the solution obtained by dissolving 10g sugar in
140g water
OR
A solution
of 20 cm3 of alcohol is dissolved in 80cm3 of water.
Calculate the concentration (v/v) of solution.
28. 10M HNO3 solution is
available in laboratory. How would you prepare 500 cm3 of 0.1M
solution?
OR
A
sample of sulphuric acid has the molarity 20M. How many cm3 of
solution should you use to prepare 500 cm3 of 0.5M H2SO4? (Answer; 12.5cm3)
29. The 800 cm3 of a gas is enclosed in a container
under a pressure of 750 mm. If the volume is reduced to 250 cm3, what will be the pressure?
OR
A
sample of Hydrogen gas has a volume of 350 cm3 at 40 C. If gas is
allowed to expand up to 700 cm3 at constant pressure. Find out its final temperature? (answer; 626 K)
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